She is then expected to deliver a farewell speech at 10.15am as her time as the shortest-serving leader in British history draws to a close.
Ms Truss will then travel to Buckingham Palace for her final audience with King Charles.
It will then be Mr Sunak’s turn to go to the palace, and the monarch will invite him to form the next government.
After officially being appointed as prime minister, the new Conservative Party leader is expected to then travel back to Downing Street.
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He will then make a public address on the steps of Number 10 at about 11.35am.
Mr Sunak won the leadership raceyesterday after Penny Mordaunt bowed out at the eleventh hour – having failed to get the 100 nominations from Tory MPs required by the 2pm deadline.
Sources in the Mordaunt camp said she got 90 nominations, though the number of those who publicly announced their backing of her fell far short of this.
“We all owe it to the country to each other and to Rishi to unite and work together for the good of the nation. There is much work to be done,” Ms Mordaunt said in a tweet.
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Mr Sunak is the UK’s first Hindu prime minister, the first of Asian heritage, and the youngest for more than 200 years at the age of 42.
The title of youngest ever prime minister belongs to William Pitt the Younger, who was just 24 when he took office in 1783. Tony Blair was 43.
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6:39
Three PMs in three months: A timeline
In his first comments after winning the contest, Mr Sunak said he was “humbled and honoured” that Tory MPs had chosen him to lead the party and the nation – describing it as the “greatest privilege in my life”.
Mr Sunak also paid tribute to outgoing prime minister Liz Truss for her “dedicated public service” in a brief speech at the Conservative Party headquarters in Westminster.
“The United Kingdom is a great country, but there is no doubt we face a profound economic challenge,” he said.
“We now need stability and unity, and I will make it my utmost priority to bring our party and our country together.”
NATO is to bolster Europe’s eastern flank, including the use of UK military resources, after Russia’s “reckless and unacceptable” violation of Polish airspace.
NATO Secretary-General Mark Rutte announced operation ‘Eastern Sentry’ on Friday, involving the deployment of equipment on the border with Belarus, Russia and Ukraine to deter potential Russian aggression.
Poland shot down Russian drones which flew over the country on Wednesday, something the military alliance has portrayed as an attempt by Moscow to test NATO’s military response.
It underlines long-held concerns about the potential expansion of Russia’s three-year war in Ukraine.
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2:11
Michael Clarke: Russia looking to frighten NATO
Russia said its drones went astray because they were jammed, but European leaders believe the incursions were a deliberate provocation by Russia.
“It’s reckless and unacceptable. We can’t have Russian drones entering allied airspace,” Mr Rutte told a news conference.
Image: Mark Rutte described Russian drones entering Polish airspace as ‘reckless’. Pic: Reuters
He added that allies, including the UK, France, Germany and Denmark, have so far committed to the mission with others set to join.
In a statement, the UK’s Ministry of Defence said: “The UK is fully committed to playing our part in NATO’s Eastern Sentry following the reckless and dangerous airspace violations by Russia”. It added that the details of the UK’s contribution would be announced soon.
Ms Cooper described her trip, which included a meeting with the country’s president, Volodymyr Zelenskyy, as a demonstration of solidarity with Ukraine.
“The UK will not stand idly by as Putin continues his barbaric invasion of Ukraine,” Ms Cooper said, noting what she said was the Russian president’s “complete disregard for sovereignty” by sending drones into NATO airspace.
Image: Yvette Cooper met Volodymyr Zelenskyy in Kyiv on Friday. Pic: Valentyn Ogirenko/Reuters
Image: Pic: Valentyn Ogirenko/Reuters
Prince Harry also made a surprise visit to Kyiv on Friday, where he met with wounded service members.
NATO already has substantial forces in eastern Europe, including thousands of troops, but the alliance did not explain how many additional forces would be involved in the new operation.
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1:54
Prince Harry’s surprise visit to Ukraine
Speaking at the alliance’s Brussels headquarters, US General Alexus Grynkewich told reporters the additional resources will enable the alliance to “plug gaps in the line” and concentrate forces wherever they’re needed while improving communications across NATO’s entire eastern flank.
NATO detailed a modest number of additional military assets – including two F-16 fighter jets and a frigate from Denmark, three Rafale fighter jets from France and four Eurofighter jets from Germany.
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Meanwhile, new measures were announced by the UK against Russia on Friday.
They included bans on 70 vessels the UK says are part of Russia’s “shadow fleet” that transports Russian oil in defiance of sanctions.
Some 30 individuals and companies – including Chinese and Turkey-based firms – were also sanctioned for their part in supplying Russia with electronics, chemicals, explosives and other weapons components.
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Thousands of troops are taking part in a joint military exercise between Russia and Belarus, as tensions with the EU run high following a Russian drone incursion into Polish airspace earlier this week.
The Zapad joint military exercise which began on Friday will involve drills in both Russia and Belarus as well as in the Baltic and Barents seas, the Russian defence ministry said.
Belarusian defence officials initially said about 13,000 troops would participate in the drill, but in May, its defence ministry said that would be cut nearly in half.
It comes just two days after Poland, with support from its NATO allies, shot down Russian drones over its airspace.
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Poland’s Prime Minister Donald Tusk on Friday morning hit back at a suggestion by US President Donald Trumpon Thursday that the incursion may have been a “mistake”.
He said in a post on X: “We would also wish that the drone attack on Poland was a mistake. But it wasn’t. And we know it.”
Russia said its forces had been attacking Ukraine at the time of the incursions and that it had not intended to hit any targets in Poland.
Friday also saw Foreign Secretary Yvette Cooper travelling to Ukraine’s capital of Kyiv on the same day the UK announced fresh sanctions against Moscow.
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Prince Harry was also in Kyivfor a surprise visitto help with the recovery of military personnel seriously injured in the three-year war with Russia.
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0:31
Prince Harry arrives in Kyiv
Ms Cooper, who was appointed foreign secretary last week, posted about her visit on X saying: “The UK’s support for Ukraine is steadfast. I am pleased to be in Kyiv on my first visit as Foreign Secretary.”
The UK’s new sanctions include bans on 70 vessels that Britain says are part of Russia’s “shadow fleet” that transports Russian oil in defiance of sanctions already in place.
Image: Yvette Cooper with Volodymyr Zelenskyy in Kyiv. Pic: Valentyn Ogirenko/PA
Some 30 individuals and companies – including Chinese and Turkey-based firms – have also been sanctioned for their part in supplying Russia with electronics, chemicals, explosives and other weapons components.
Her visit coincides with the UK launching a new package of Russia-related sanctions targeting ships carrying Russian oil as well as companies and individuals supplying electronics, chemicals and explosives used to make Russian weapons.
It comes as Russia and Belarus began a major joint military exercise on on NATO’s doorstep on Friday, just two days after Poland, with support from its NATO allies, shot down suspected Russian drones over its airspace.
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0:29
Drones shot down in Poland
The Zapad-2025 exercise – a show of force by Russia and its close ally – will involve drills in both countries and in the Baltic and Barents seas, the Russian defence ministry said.
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Meanwhile on the frontline, Russian defence systems intercepted and destroyed 221 Ukrainian drones overnight, including nine over the Moscow region, the ministry said on Friday.
The duke told the Guardian while on an overnight train to Kyiv: “We cannot stop the war but what we can do is do everything we can to help the recovery process.
“We can continue to humanise the people involved in this war and what they are going through.
“We have to keep it in the forefront of people’s minds. I hope this trip will help to bring it home to people because it’s easy to become desensitised to what has been going on.”
Harry, who served two tours in Afghanistan, previously travelled to Ukraine in April, when he visited war victims as part of his work with wounded veterans.
The prince visited the Superhumans Center, an orthopaedic clinic in Lviv that treats and rehabilitates wounded military personnel and civilians.
Earlier this week, Harry said the King is “great” after he reunited with him at Clarence House for a private tea.
It was their first meeting in 19 months and lasted just 54 minutes.